Synthesis, characterization and adsorption studies of nano-composite hydrogels and the effect of SiO2on the capacity for the removal of Methylene Blue dye

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TEMEL S., YAMAN E., ÖZBAY N., GÖKMEN F. Ö.

Journal of the Serbian Chemical Society, cilt.85, sa.7, ss.939-952, 2019 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 85 Sayı: 7
  • Basım Tarihi: 2019
  • Doi Numarası: 10.2298/jsc190517114t
  • Dergi Adı: Journal of the Serbian Chemical Society
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.939-952
  • Anahtar Kelimeler: Acrylic acid hydrogels, SiO2nanoparticles, Textile dyes, Vinyl pyrrolidone, Wastewater treatment
  • Bilecik Şeyh Edebali Üniversitesi Adresli: Evet

Özet

© 2019 Serbian Chemical Society. All rights reserved.Nanocomposite hydrogels were produced by free radical polymerization of acrylic acid and N-vinylpyrrolidone in the presence of SiO2nanoparticles. The chemical and morphological structures of the hydrogels were determined using Fourier transform infra-red spectroscopy (FT-IR) and field emission scanning electron microscopy (FESEM). The nanocomposite hydrogels were used for the adsorption and desorption of Methylene Blue dye from wastewater. Wastewater was referred to distilled water that contained Methylene Blue dye under laboratory conditions. The carbon, hydrogen and nitrogen contents of the dye, hydrogels and dye-adsorbed hydrogels were determined by elemental analysis. The influences of SiO2nanoparticles and copolymerization on the adsorption capacity were studied. The maximum dye removal of 98.3 % was obtained with AA-co-VP (3:1) copolymeric hydrogel. The synthesized hydrogels could be evaluated as adsorbents in wastewater treatment, effectively.