Co-Mo-Se ternary chalcogenide thin film coated p -Si photocathode for efficient solar hydrogen production

KURU C.

Functional Materials Letters, cilt.14, sa.1, 2021 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 14 Sayı: 1
  • Basım Tarihi: 2021
  • Doi Numarası: 10.1142/s1793604721510024
  • Dergi Adı: Functional Materials Letters
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Compendex, INSPEC, Metadex
  • Anahtar Kelimeler: Catalyst, cobalt, hydrogen, molybdenum selenide, ternary chalcogenides, water splitting
  • Bilecik Şeyh Edebali Üniversitesi Adresli: Evet

Özet

© 2021 World Scientific Publishing Company.Photoelectrochemical (PEC) water splitting holds a great promise for clean and sustainable hydrogen production. In this study, the PEC performance of Co-Mo-Se ternary chalcogenide thin film coated Si photocathodes is investigated. The Co-Mo-Se films with various Co/Mo atomic ratios were prepared by thermal selenization of sputter deposited Co-Mo alloy films. Among the photocathodes, the Co-Mo-Se (3:10)/p-Si surpasses the PEC performance of the MoSe2/p-Si with an onset potential of +124 mV vs. reversible hydrogen electrode (RHE), a photocurrent density of -22.68 mA/cm2 at zero overpotential and good stability over 6 h period of test. The superior performance of the Co-Mo-Se (3:10)/p-Si is ascribed to the high catalytic activity of the film in hydrogen evolution reaction (HER) and efficient collection of photogenerated charge carriers. Such ternary chalcogenide thinfilms offer exciting opportunities for many applications in which the physicochemical properties can be tuned by changing the relative amount of the solute atoms.