Synthesis and characterization of spiro-, ansa-, and spiro-ansa-cyclic derivatives of cyclotetraphosphazene with the reactions of pentane-1,5-diol

TÜRE S.

Phosphorus, Sulfur and Silicon and the Related Elements, cilt.191, sa.1, ss.129-139, 2016 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 191 Sayı: 1
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1080/10426507.2015.1054483
  • Dergi Adı: Phosphorus, Sulfur and Silicon and the Related Elements
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.129-139
  • Anahtar Kelimeler: ansa compounds, NMR studies, Octachlorocyclotetraphosphazatetraene, pentane-1,5-diol, spiro compounds, spiro-ansa compounds
  • Bilecik Şeyh Edebali Üniversitesi Adresli: Evet

Özet

© 2016 © Taylor & Francis Group, LLC.The reactions of octachlorocyclotetraphosphazatetraene, N4P4Cl8 (1) with difunctional aliphatic reagent, HO-(CH2)5-OH (3) have aroused a good deal of attention, and four types of products have been realized: one 2-open chain-(1'-oxy-5'-hidroxy-pentane)-2,4,4,6,6,8,8-heptachlorocylotetraphosphazatetraene, N4P4Cl7[O(CH2)5OH] (4); one 2,2-mono-spiro-(1',5'-pentanedioxy)-4,4,6,6,8,8-hexachlorocyclotetraphosphazatetraene, N4P4Cl6[O(CH2)5O] (5); its isomers 2,4-mono-ansa-((1',5'-pentanedioxy)-2,4,6,6,8,8- hexachlorocyclotetraphosphazatetraene (6) and 2,6-mono-ansa-(1',5'-pentanedioxy)-2,4,6,6,8,8-hexachlorocyclotetraphosphazatetraene (7); one 2,2,6,6-dispiro-(1',5'-pentanedioxy)-4,4,8,8-tetrachlorocyclo- tetraphosphazatetraene, N4P4Cl4[O(CH2)5O]2(8); two isomeric 2,4,6,8-bisansa-(1',5'-pentanedioxy)-2,4,6,8-tetrachlorocyclotetraphosphazatetraene (9) and 2,6,4,8-bisansa-(1',5'-pentanedioxy)-2,4,6,8-tetrachloro-cyclotetraphosphazatetraene (10); one 4,4,8,8-dispiro-2,6-ansa- (1',5'-pentanedioxy)-2,6-dichlorocyclotetra-phosphazatetraene, N4P4Cl2[O(CH2)5O]3(11), one 2,2,4,4,6,6-trispiro-(1',5'-pentanedioxy)-8,8-dichlorocyclo-tetraphosphazatetraene, N4P4Cl2[O(CH2)5O]3 (12); and a 2,2,4,4,6,6,8,8-tetraspiro-(1',5'-pentanedioxy)-cyclotetraphosphazatetraene derivative, N4P4[O(CH2)5O]4, (13). The respective structures were deduced by means of elemental analysis, mass spectrum, and 31P, 1H, and 13C nuclear magnetic resonance spectroscopic investigations.