Synthesis of an F-BODIPY [2]catenane using the chemistry of bis(dipyrrinato)metal complexes

NİŞANCI, Bilal; Sahinoglu, Sinem; Tuner, Esra; ARK, MUSTAFA; Kani, Ibrahim; DAŞTAN, Arif; BOZDEMİR, Özgür

doi:10.1039/c7cc07021g

Synthesis of an F-BODIPY [2]catenane using the chemistry of bis(dipyrrinato)metal complexes

NİŞANCI B., Sahinoglu S., Tuner E., ARK M., Kani I., DAŞTAN A., ...Daha Fazla

Chemical Communications, cilt.53, sa.92, ss.12418-12421, 2017 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 53 Sayı: 92
Basım Tarihi: 2017
Doi Numarası: 10.1039/c7cc07021g
Dergi Adı: Chemical Communications
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.12418-12421
Bilecik Şeyh Edebali Üniversitesi Adresli: Hayır

Özet

ML2 type complexes of an olefin terminated 5H-dipyrrin ligand can be subjected to twofold ring closing metathesis to give bis(dipyrrinato)copper(ii) and bis(dipyrrinato)zinc(ii) [2]catenates. Demetalation of the copper(ii) [2]catenate with KCN/N2H4·H2O gave the corresponding bis(dipyrrin) [2]catenand. The boron difluoride complex of this bis(dipyrrin) was obtained as the first fluorescent F-BODIPY [2]catenane.