Luminescence of Molecular Nitrogen Nanoclusters Containing Stabilized Atoms
Journal of Physical Chemistry A, cilt.121, sa.47, ss.9045-9057, 2017 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 121 Sayı: 47
- Basım Tarihi: 2017
- Doi Numarası: 10.1021/acs.jpca.7b09661
- Dergi Adı: Journal of Physical Chemistry A
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.9045-9057
- Bilecik Şeyh Edebali Üniversitesi Adresli: Evet
Özet
© 2017 American Chemical Society.We studied the luminescence of molecular nitrogen nanoclusters containing stabilized nitrogen, oxygen, hydrogen, and deuterium atoms. Optical spectra were observed during the destruction of these ensembles of nanoclusters accompanied by a rapid release of chemical energy stored in the samples. Several interesting features were observed including a broad band near λ ≈ 360 nm, which was identified as emission corresponding to 2Ag→1Ag transition of N4(D2h) polymeric nitrogen. Also the sharp lines at λ ∼ 336 and 473 nm were observed, and their assignments to ND radicals are discussed.