Green-synthesized AgNP/bc-anchored cellulose acetate composites derived from waste textiles: physicochemical, biological, and filtration performance for advanced applications


GÜMÜŞ H., Keskin S. Y., Büyükkıdan B., Bulut E., Avcı A., Zaaroura A.

Polymer Bulletin, cilt.83, sa.6, 2026 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 83 Sayı: 6
  • Basım Tarihi: 2026
  • Doi Numarası: 10.1007/s00289-026-06392-8
  • Dergi Adı: Polymer Bulletin
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Chemical Abstracts Core, Chimica, Compendex, INSPEC
  • Anahtar Kelimeler: Ag particle, Antimicrobial effect, Biocarbon, Hydrolyzed cellulose, Waste recycling
  • Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
  • Bilecik Şeyh Edebali Üniversitesi Adresli: Evet

Özet

Cellulose acetate has gained remarkable interest due to its biocompatibility, easy formability, and moderate physical properties. In this study, silver particles synthesized by two different green methods were anchored with biocarbon (AgP-bc) in cellulose acetate (CA), which was synthesized from textile waste using a chemical route. The effects of AgP preparation methods reduced with quince extract in solution (Method I) and powder form (Method II) were monitored and compared mainly by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and X-ray diffraction (XRD) analyses. Water uptake, porosity, and water contact angle measurements were carried out, and the surface areas of the composites were determined by multi-point BET analysis. Antimicrobial studies were conducted to evaluate the biological activity of the composites. Cellulose acetate was successfully prepared from textile waste, and the methods used in AgP preparation significantly influenced both the physical and antimicrobial properties of the composites. AgP-bc-CA1 exhibited a high BET surface area and measurable, supportive antimicrobial activity against Escherichia coli O157:H7 and Staphylococcus aureus. The flat-sheet composite membranes achieved a flux of 51.3 L·m⁻²·h⁻¹·bar⁻¹ and a methyl orange (MO) rejection efficiency of 54.2% during filtration. Smooth-surfaced AgP-bc-CA1 demonstrated the best fouling resistance. The composites, produced as flat-sheet membranes with homogeneous AgP distribution enabled by the biocarbon additive, are suitable for filtration applications, with antimicrobial activity serving as a supportive functional property.