Nanocrystalline PbS thin film produced by alkaline chemical bath deposition: Effect of inhibitor levels and temperature on the physicochemical properties

ŞİMŞEK V., ÇAĞLAYAN M. O.

International Journal of Materials Research, cilt.114, sa.12, ss.1047-1057, 2023 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 114 Sayı: 12
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1515/ijmr-2022-0491
  • Dergi Adı: International Journal of Materials Research
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, PASCAL, Aerospace Database, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, Metadex, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.1047-1057
  • Anahtar Kelimeler: Chemical bath deposition, Inhibitor concentration, Nanocrystalline, PbS, Temperature effect
  • Bilecik Şeyh Edebali Üniversitesi Adresli: Evet

Özet

In this study, nanocrystalline PbS film coating on a glass slide was done using the chemical bath deposition method. PbS film was deposited in an alkaline solution using Pb(NO3)2, CS(NH2)2, and the inhibitor (Na2S2O3) for 30-120 min at room temperature (25 °C) and 40 °C, and inhibitor levels were investigated in the range of 3.2 mM-12.7 mM. The physicochemical properties of the obtained thin films were investigated by scanning electron microscopy, MAPPING, atomic force microscopy, fourier-transform infrared spectroscopy, water contact angle and X-ray diffraction analyses. The relationship between nanocrystallite size, distribution, pin-hole development, and synthesis conditions were examined using image processing and surface response methodology. The band gap of the produced PbS thin film was calculated using FT-IR analysis results (0.41 eV).